By David R. Bassett and Alvin E. Hamielec (Eds.)
content material: Latex particle nucleation and progress / Robert M. Fitch --
Latex particle stabilization / R.H. Ottewill --
Well-characterized monodisperse polystrene latexes as version colloids / J.W. Vanderhoff --
Characterization of latex debris by way of mild scattering / R.L. Rowell and J.R. Ford --
The molecular weight distributions of emulsion polymers / Donald H. Napper, Gottfried Lichti, and Robert G. Gilbert --
at the optimum reactor style and operation for non-stop emulsion polymerization / Mamoru Nomura and Makoto Harada --
Emulsifier-free emulsion copolymerization of styrene with acrylamide and its derivatives / Haruma Kawaguchi, Yoshishige Sugi, and Yasuji Ohtsuka --
Polyelectrolyte-stabilized latices / Richard Buscall and Terence nook --
Mechanical and chemical balance of polymer latices / D.C. Blackley --
Stabilization in nonaqueous radical dispersion polymerization with AB block copolymers of polystyrene and poly(dimethyl siloxane) / J.V. Dawkins, G. Taylor, S.P. Baker, R.W.R. Collett, and J.S. Higgins --
The formation of coagulum in emulsion polymerization / J.W. Vanderhoff --
influence of spray drying parameters on polyvinyl chloride resin particle dimension distribution and plastisol rheology / D.J. Hoffmann and P.M. Saffron --
Surfactant interactions in polyvinyl acetate and poly (vinyl acetate-butyl acrylate) latexes / B.R. Vijayendran, T. Bone, and C. Gajria --
speedy density gradient centrifugation of polymer latices / H. Lange --
the connection among the electrophoretic mobility and the adsorption of ions on polystyrene latex / C.M. Ma, F.J. Micale, M.S. El-Aasser, and J.W. Vanderhoff --
suggestions for measuring particle swelling of carboxylic emulsion polymers / D.R. Bassett, E.J. Derderian, J.E. Johnston, and T.B. MacRury --
gentle scattering reviews of the inner constitution of emulsion polymer debris / J.R. Ford, R.L. Rowell, and D.R. Bassett --
education and characterization of alkali-swellable carboxylated latexes / S. Nishida, M.S. El-Aasser, A. Klein, and J.W. Vanderhoff --
Emulsion polymerization kinetics : chain entanglements and glassy-state transition / B. Harris, A.E. Hamielec, and L. Marten --
Diffusion-controlled kinetics within the emulsion polymerization of styrene and methyl methacrylate / D.C. Sundberg, J.Y. Hsieh, S.K. Soh, and R.F. Baldus --
Polymerization kinetics through precision densimetry / K.J. Abbey --
The influence of nonreactive ingredients at the kinetics of emulsion polymerization / A.R.M. Azad, R.M. Fitch, and M. Nomura --
Nonuniform emulsion polymers : method description and polymer houses / D.R. Bassett and K.L. Hoy --
Nonuniform emulsion polymers : carbon-13 NMR spectroscopy / J.E. Johnston, D.R. Bassett, and T.B. MacRury --
Morphology of two-stage latex debris : polystyrene and styrene-butadiene copolymer pair platforms / D.I. Lee --
New layout for generating constant-composition copolymers in emulsion polymerization : comparability with different methods / A. Guyot, J. Guillot, C. Pichot, and L. Rios Guerrero --
conception of compartmentalized free-radical polymerization reactions / D.C. Blackley --
A reinvestigation of vinyl acetate emulsion polymerization : isotope impression / M.H. Litt and K.H.S. Chang --
Catalysis of thermal initiation of styrene emulsion polymerization by means of emulsifiers / Zaid F.M. stated, Sabah A. Hassan, and Alexander S. Dunn --
Latex seed particle progress at excessive surfactant floor insurance / J.R. Erickson and R.J. Seidewand --
online tracking of emulsion polymerization reactor dynamics / F.J. Schork and W.H. Ray --
regulate of particle measurement distribution via emulsifier metering in line with cost of conversion / Daniel L. Gordon and Karl R. Weidner --
A simulation research at the use of a dead-time repayment set of rules for closed-loop conversion regulate of continuing emulsion polymerization reactors / Kenneth W. Leffew and Pradeep B. Deshpande --
Experimental research of the seeded polymerization of vinyl acetate in a tube / C.K. Lee and T.H. Forsyth.
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Additional resources for Emulsion Polymers and Emulsion Polymerization
W i t h pH b e t w e e n 2 and 4. I t seems l i k e l y t h a t t h e s e a r o s e f r o m t h e i n i t i a t o r and were e i t h e r s u c c i n i c or p r o p i o n i c a c i d attached to fluorocarbon chains or f l u o r o c a r b o n c a r b o x y l i c a c i d s . 38 yC cm e q u i v a l e n t t o one c h a r g e d g r o u p p e r 42 nm . The c . c . c . 5 x 10 mol dm ammonium p e r f l u o r o - o c t a n o a t e t o t h e l a t e x i n c r e a s e d i t s s t a b i l i t y t o t h e a d d i t i o n o f s o d i u m c h l o r i d e and aluminium n i t r a t e .
Total interaction involving electrostatic repulsion and van der Waals attraction. LONG CHAINS-IONIC Figure 2. LONG CH AINS-NONIONIC Schematic of the nature of the surface on various types of latex particles OTTEWILL 2. Latex static potential, Particle 35 Stabilization , w h i c h c a n be e i t h e r p o s i t i v e o r n e g a t i v e , depending on the s u r f a c e groupings, r e l a t i v e t o e a r t h . I n more q u a n t i t a t i v e t e r m s c a n now b e t a k e n i n c o n j u n c t i o n w i t h t h e p r o p e r t i e s o f t h e medium t o o b t a i n a n e x p r e s s i o n f o r t h e e l e c t r o s t a t i c r e p u l s i v e p o t e n t i a l energy, V .
Once t h e n e g a t i v e c h a r g e s o n t h e p a r t i c l e s u r f a c e h a v e b e e n n e u t r a l i s e d f u r t h e r a d s o r p t i o n of the s u r f a c t a n t occurs v i a the t a i l o n t o t h e h y d r o p h o b i c p a t c h e s o f t h e s u r f a c e and a l s o b y a s s o c i a t i o n of the hydrocarbon c h a i n s . Detailed adsorption s t u d i e s h a v e b e e n r e p o r t e d o n p o l y s t y r e n e l a t i c e s ( 3 6 ) . The a d d i t i o n a l a d s o r p t i o n p r o v i d e s a p o s i t i v e charge t o the p a r t i c l e s and r e s t a b i l i z a t i o n o c c u r s .