By William J. Koros
content material: Barrier polymers and constructions : review / William J. Koros --
basics of gasoline diffusion in rubbery and glassy polymers / S.A. Stern and S. Trohalaki --
results of structural order on barrier houses / D.H. Weinkauf and D.R. Paul --
shipping of plasticizing penetrants in glassy polymers / Alan R. Berens --
constitution of amorphous polyamides : impact on oxygen permeation homes / Timothy D. Krizan, John C. Coburn, and Philip S. Blatz --
delivery of penetrant molecules via copolymers of vinylidene chloride and vinyl chloride / J. Bicerano, A.F. Burmester, P.T. DeLassus, and R.A. Wessling --
fuel shipping via bisphenol-containing polymers / John C. Schmidhauser and Kathryn L. Longley --
Water delivery via polymers : requisites and designs in nutrients packaging / Leonard E. Gerlowski --
Barrier homes of ethylene-vinyl alcohol copolymer in retorted plastic nutrients boxes / Boh C. Tsai and James A. Wachtel --
Retortable nutrition programs containing water-sensitive oxygen barrier / M.M. Alger, T.J. Stanley, and J. Day --
functionality of high-barrier resins with platelet-type fillers : results of platelet orientation / T.C. Bissot --
Permeability of aggressive oxygen-barrier resins : orientability and influence of orientation / R. Shastri, H.C. Roehrs, C.N. Brown, and S.E. Dollinger --
Polymer blends : morphology and solvent obstacles / P.M. Subramanian --
development in barrier houses of polymers through sulfonation and reductive metallization / W.E. Walles --
Fluorinated high-density polyethylene barrier bins : functionality features / J.P. Hobbs, M. Anand, and B.A. Campion --
Packaging of juices utilizing polymeric barrier boxes / J. Miltz, C.H. Mannheim, and B.R. Harte --
lack of style compounds from aseptically processed foodstuff items packaged in aseptic bins / A.P. Hansen and D.K. Arora --
Diffusion and sorption of linear esters in chosen polymer movies / G. Strandburg, P.T. DeLassus, and B.A. Howell --
Sorption and diffusion of monocyclic fragrant compounds via polyurethane membranes / U. Shanthamurthy Aithal, Tejraj M. Aminabhavi, and Patrick E. Cassidy --
Toluene diffusion in usual rubber / Lawrence S. Waksman, Nathaniel S. Schneider, and Nak-Ho Sung.
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Extra resources for Barrier Polymers and Structures
E ^ in terms of activation f and used unsymmetrical Anysas gases in (15j Using and Barrer's found be in zone theory be 25 to attributed to low the tested sources, to calculations ones, fluorocarbon other other Ε _ («Ε,+Ε , ) t o have a minimum f o r d b ι T h i s can pressure from polymer too neighbors, the bend penetrant energies a p p r o p r i a t e to the d i f f u s i o n were internal motions, diffusion experience Brandt f between experimental for between t h e c h a i n s . energy expressing polyethylene than of activated which + Ε.
Range. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1990. 2. 2 1/TxlO Figure 10. 4 1 M u t u a l d i f f u s i o n c o e f f i c i e n t s , of t h e two m o l e c u l a r p o p u l a t i o n s o f a f l u o r e s c e n t dye d i s p e r s e d i n p o l y ( 1 - t r i m e t h y l - l - p r o p y n e ) p l o t t e d as f u n c t i o n s o f r e c i p r o c a l absolute temperature. The t e c h n i q u e u s e d was l a s e r f l u o r e s c e n c e p h o t o b l e a c h i n g r e c o v e r y .
T h e polymer, during Pace and D a t y n e r of penetrant dissolved causing t h e experiment. argue t h a t t h e s i g n i - by Henry's-law a relaxation They mode of the i n i t i a l further assert that, with decreasing c^ w i l l d i s p l a y t h e temperature dependence m e n t i o n e d above. estimated a statistical-mechanical values o f t h e model p a r a m e t e r s . ment was o b t a i n e d between and experimental poly(ethylene styrene. only analysis, data solubility (Tg-T), t h e a p p a r e n t Pace and D a t y n e r Semiquantitative data micro- since the p l a s t i c i z a t i o n e f f e c t decreases Using acts to generated from have agree- t h e model fo terephthalate) F o r polymers with and, t o a flexible lesser extent, s i d e groups, f o r poly t h e agreement was qualitative.