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This source for either clinicians and scientists goals to hide cutting-edge findings suitable to mobile and molecular approaches underlying cardiac fibrosis together with easy parts of constitution, functionality, prognosis and remedy.
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Additional info for Atlas of Plastics Additives
1650 895-885 ca. 3020 ca. 4 Characteristic absorption band combinations/partial spectra of aromats Vibrating group Assignment Range/cm"1 Intensity Remark AU aromats v(ring-H) combination vibration v(ring) v(ring) 3080-3010 2000-1700 w-m vw-w ca. 1600 1510-1470 w-sb w-sd 1150-1000 var Several peaksa Number and position depend on substitution Sometimes split0 Wavenumber depends on substituente Difficult to identify S Five adjacent H atoms 6(ring-H) Benzene derivatives (-substituted) monoY(ring-H)f Y(ring) 6(ring 1,2-diy(ring-H) 6(ring) 1,3-diy(ring-H) Y(ring) y(ring-H) 1,4-di1,2,3-tri1,2,4-tri1,3,5-tri1,2,3,4-tetra1,2,3,5-tetra1,2,4,5-tetra- 6(ring) y(ring-H) 6(ring) y(ring-H) 6(ring) y(ring-H) penta6(ring) a b c d e f 750±15 697±11 625-605 750±10 550-500 780110 690±15 815±20 780-760 745-705 885-870 830-800 865-810 730-675 810-800 585-565 850-840 580-505 ca.
1055 ca. 915 ca. 1420 ca. 1090 ca. 1030 ca. 830 3020 2980 1400 ca. 1180 880 ca. 1415 ca. 1280 1165+1145 ca. 665 ca. 1785 ca. 1230 ca. 1170 ca. 690 1335-1320 1140-1130 700-600 1265-1200 550-500 455-440 w-m m-s 1300-1240 ca. 650 ca. 730 ca. 690 ca. 1250 ca. 20 Continue Vibrating group R3C-Cl Range/cm"1 Intensity ca. 610 1240-1225 1160-1145 ca. 620 570-560 1100-1090 1080-1070 1060-1030 ca. 680 640-630 var var m sh 1255-1225 650-640 570-555 1085-1070 1030-1020 680-655 605-595 S-VS m m m-s m-vst m-s m-s numerous activated skeleton vibrations m- and p-substitution o-substitutionc o- and m-substitution p - substituted v(C-CI) 1250-1185 1190-1170 m-vs m-s dependent on chain length not always present v(C-I)d 600-590 505-500 vw-m C2H5I: 500 Assignment v(C-CCl) v(C-Cl) Ar-Cl 5(ring-H)/ v(ring-Cl) v(ring-Cl) C-Br aliphatic R-CH2-Br Ar-Br R-I aliphatic n-alkyl vCCBrcoCH2Br v(C-Br) 6(ring-H/ v(ring-Br) Remark S-VS w-m m-s S m m-s m-s m-s p - substitution0 m-substitutionc o-substitutionc o- and m-substitution p - substitution W-VW i-alkyl numerous activated skeleton vibrations 655-640 v(Ar-I) 465-430 m-vs sh w-s sh Ar-I a CF groups are vibrationally strongly coupled with neighbouring structures.
Interestingly, the IRS of a molecule or ion becomes simpler with increasing symmetry. Thus, the frequent XY4 species possess nine FV; due to selection rules and degeneracy only two IR bands should be observable. g. cations a degeneration may be lifted. This is quite frequent in the case of sulfates; the band around 1100 cm"1 is then split into three components. In addition, weak to medium bands may show up where Raman active FV exist. g. the distinction between salts with the same anion. In the case of solids, the crystallographic elementary cell serves for the calculation of the FV; this is the reason why polymorphous modifications frequently can be distinguished by their IRS.